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Octant Rule - Download as PDF File (.pdf), Text File (.txt) or read online. . Rule type Applications Sector Saturated ketones (the axial haloketone and octant rules). . Documents Similar To Octant Rule. SM-14. Uploaded by. prudentescent.. 14 that, in many instances, very characteristic rotatory dispersion curves were. (I) . axial haloketone rule would predict a strongly negative Cotton effect for.. Page 14 . the Octant "rule predicts a positive Cotton effect for conformation. . .and negative . The "axial halo ketone ruJ.e" states the matter as .follows: (1).. 15.4 Empirical and semiempirical rules Optically active chromophores are broadly . 15.4.1 The axial haloketone rule The axial haloketone rule (Djerassi and.. Download as DOC, PDF, TXT or read online from Scribd. Flag for . The Axial Haloketone Rule and the Octant Rule for Saturated etones. The octant rule is the.. been guided by the Octant Rule, ever since the Harvard discussions of July and. August, 1958.2 . more restricted scope, the axial a-haloketone rule9. ' C. Djerassi and . (c) 14,Ssteroids (i.e. CD-cis fused steroids)-because the conformation.. A haloketone in organic chemistry is a functional group consisting of a ketone group or more . This page was last edited on 18 April 2018, at 14:21 (UTC). Text is available under the Creative Commons Attribution-ShareAlike License; additional terms may.. lycopodine was assigned by application (l3,14) of the octant rule (15) and of the axial haloketone rule (2). As is predicted by the octant rule, both lycopodine and.. The selection rules for optical activity are also stringent in . effect signs in molecules, i.e., the axial haloketone rule and the . 14: ORD photomultiplier.. Download full text in PDFDownload . Volume 14, 1994, Pages 131-174 . In applications of the Octant Rule, when the absolute configur

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